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Beilstein J. Org. Chem. 2016, 12, 2719–2730, doi:10.3762/bjoc.12.268
Graphical Abstract
Figure 1: Electron-transfer initiated activation of α-diketones (background) and present study.
Scheme 1: Proposed dianionic pathway for the cross-benzoin-like reaction of benzils 1 with aldehydes 2 under ...
Scheme 2: Trapping experiment.
Figure 2: Conversion of the 1a/2a coupling in microreactor R5 operated for 150 h at 50 °C.